Determination of Ga,Ge, Mo,Ag, Cd,In, Sn,Sb, W,Tl and Bi in USGS Whole‐Rock Reference Materials by Standard Addition ICP‐MS          下载免费PDF全文

Richard M. Gaschnig  Roberta L. Rudnick  William F. McDonough 《Geostandards and Geoanalytical Research》2015,39(3):371-379

A procedure for determining a wide range of chalcophile and siderophile elements in typical crustal rocks using standard addition and ICP‐SFMS (inductively coupled plasma sector field mass spectrometry) is presented. New results for Ga, Ge, Mo, Ag, Cd, In, Sn, Sb, W, Tl and Bi abundances in USGS whole‐rock reference materials AGV‐2, BHVO‐1, BIR‐1, G‐2, GSP‐1 and W‐2 are reported using this analytical procedure. Intermediate precision of means based on multiple dissolved aliquots of each USGS reference material was 10% RSD or better for Ga, Ge, In and Sn in all, and similarly good for Ag, Cd, Sb, Tl and Bi in most reference materials. Poorer intermediate precision of Mo and W measurements in several reference materials is probably due to higher analytical blanks on these elements and powder heterogeneity due to a sulfide‐related nugget effect in the specific case of Mo in GSP‐1. Results for all elements fell within the range of available published data with the exception of Ag, which yielded systematically higher concentrations than found in the literature for five of the six reference materials, likely reflecting interference from unresolved polyatomic species.  相似文献   

Thermal analysis of energy piles in sand     

Rajni Saggu 《Geomechanics and Geoengineering》2015,10(1):10-29

The present work investigates the behaviour of geothermal energy piles in sand subjected to thermal loading and the resulting soil-structure interaction, numerically using the finite element software Abaqus and user-defined material subroutines for soil. The stress-strain response of sand has been simulated using CASM constitutive model based on critical-state soil mechanics. Detailed parametric sensitivity studies have been carried out to understand the effects of different end conditions of the pile, relative densities of the soil, coefficients of lateral earth pressure of the ground, lengths and diameters of the pile, thermal loads, coefficients of friction at the pile-soil interface, critical-state friction angles of soil, thermal conductivity of soil, specific heat of soil and thermal conductivity of the pile on the stress response of soil, deformation of the pile and soil, and strains in the pile. The results show that negative shear stress is generated in the soil at the pile-soil interface. In the pile with both ends restrained the lateral earth pressure coefficient in soil increases due to high radial strain generation. Moreover, the lateral earth pressure coefficient in soil increases with the increase in the thermal load, the coefficient of friction at the pile-soil interface and the critical-state friction angle of the soil.  相似文献   

高温熔融研制钾长石玻璃标准物质初探   总被引：1，自引：1，他引：0  

宋佳瑶  袁洪林  包志安  陈开运  贺国芬  范超 《岩矿测试》2011,30(4):406-411

激光剥蚀多接收等离子体质谱(LA-MC-ICPMS)是进行原位微区分析微量元素和同位素的重要技术之一,标准样品与样品之间的基体匹配是解决影响该技术准确分析的基体效应和分馏效应的首选方案。长石(特别是长石微区)的Pb同位素组成是示踪岩石形成和演化历史的重要途径,而LA-MC-ICPMS技术则是进行长石Pb同位素原位微区分析的关键技术,然而目前国内外尚没有合适的长石Pb同位素分析标准。文章研究探讨了利用高温炉进行原位微区分析钾长石中Pb同位素组成所用外部标准物质合成条件,结果表明,常规的74μm(200目)碎样无法得到均一的钾长石玻璃,需要将初始钾长石粉末研磨至1300目以下;高温炉合成温度为1680℃;熔融时间为2 h;采用液氮方式淬火。制成的钾长石玻璃除表面具有轻微的不均一性外,内部的Pb同位素比值为1.90779±0.00009(208Pb/206Pb,2s),0.75899±0.00004(207Pb/206Pb,2s),20.909±0.002(206Pb/204Pb,2s),15.871±0.002(207 Pb/204 Pb,2s)和39.888±0.005(208 Pb/204 Pb,2s),相应的相对标准偏差(RSD)分别为0.007%、0.008%、0.016%、0.016%和0.021%。表明利用本研究方法合成的钾长石玻璃可作为潜在的钾长石中Pb同位素组成原位微区分析外部校准物质。  相似文献   

铜镍硫化物铼-锇标准物质定值的溯源性讨论及总不确定度评估     

屈文俊  李超  杜安道 《岩矿测试》2011,30(6):664-668

对按国家一级标准物质技术规范研制的铜镍硫化物Re-Os标准物质定值的溯源性及其总不确定度进行讨论与评估。铜镍硫化物标准物质样品采用Carius管溶解,高精度的TRITON同位素质谱仪、MAT-262热电离质谱仪、四极杆等离子体质谱仪、多接收器等离子体质谱仪和高分辨四极杆等离子体质谱仪测量Re、Os含量和Os同位素比值,其中Re-Os含量可以溯源至基准物质,而187Os/188Os同位素比值可以溯源至国际纯粹与应用化学联合会(IUPAC)。在定值数据误差计算时,采用国际通用的ISOPLOT软件利用加权的方法对数据进行处理;在合成总不确定度时,考虑了物质的均匀性和稳定性,同时考虑了稀释剂标定和同位素丰度以及称量误差等影响测定因素的不确定度。标准值的不确定度由三部分组成:第一部分是通过所有参与定值数据,采用ISOPLOT软件,利用加权的方法对数据进行计算处理得到的不确定度;第二部分是物质的均匀性和稳定性的不确定度;第三部分是影响测定其他因素的不确定度。  相似文献   

Metamorphic history of the South Tibetan Detachment System,Mt. Everest region,revealed by RSCM thermometry and phase equilibria modelling   总被引：2，自引：0，他引：2  

J. M. COTTLE  D. J. WATERS  O. BEYSSAC  M. J. JESSUP 《Journal of Metamorphic Geology》2011,29(5):561-582

This study combines microstructural observations with Raman spectroscopy on carbonaceous material (RSCM), phase equilibria modelling and U–Pb dating of titanite to delineate the metamorphic history of a well‐exposed section through the South Tibetan Detachment System (STDS) in the Dzakaa Chu valley of Southern Tibet. In the hanging wall of the STDS, undeformed Tibetan Sedimentary Series rocks consistently record peak metamorphic temperatures of ～340 °C. Temperatures increase down‐section, reaching ～650 °C at the base of the shear zone, defining an apparent metamorphic field gradient of ～310 °C km^?1 across the entire structure. U–Th–Pb geochronological data indicate that metamorphism and deformation at high temperatures occurred over a protracted period from at least 20 to 13 Ma. Deformation within this 1‐km‐thick zone of distributed top‐down‐to‐the‐northeast ductile shear included a strong component of vertical shortening and was responsible for significant condensing of palaeo‐isotherms along the upper margin of the Greater Himalayan Series (GHS). We interpret the preservation of such a high metamorphic gradient to be the result of a progressive up‐section migration in the locus of deformation within the zone. This segment of the STDS provides a detailed thermal and kinematic record of the exhumation of footwall GHS rocks from beneath the southern margin of the Tibetan plateau.  相似文献   

遵义仙人岩铝土矿床地质地球化学特征     

殷科华  李克庆  朱德彬  和秀林  吴虹 《贵州地质》2011,28(1):24-29

仙人岩铝土矿床是遵义铝土矿中规模最大、以高铁铝土矿为主,产于碳酸盐岩古岩溶侵蚀面之上的沉积型一水硬铝石铝土矿床,其成矿时代属早石炭世大塘期.本文对仙人岩铝土矿床地质地球化学特征进行了初步分析,表明在大塘期前,由于加里东运动,息烽-遵义上升成陆,致使基底地层(∈-S)遭受长期的风化剥蚀,形成较为丰富的风化残积物和大小不等...  相似文献   

海泡石改性及吸附Zn²⁺研究   总被引：1，自引：0，他引：1  

刘菁  邓苗  胡子文  史佳伟 《岩石矿物学杂志》2011,30(4):716-720

金属离子型无机抗菌剂具有安全性好、抗菌广谱、时效长和耐热等许多优良性能,在许多领域有广泛的应用价值。金属离子型无机抗菌剂由金属抗菌离子和无机载体材料组成,其抗菌性能与载体材料对抗菌金属离子的吸附量有关。本文初步研究了对海泡石进行酸改性及用海泡石载抗菌锌离子(Zn2+)的两种工艺方式对海泡石结构及载Zn2+量的影响。通过原子吸收发射光谱、X射线衍射、扫描能谱电子显微镜及傅立叶变换红外光谱等技术的分析表明,用体积浓度为5%的HCL,在70℃温度下对海泡石进行酸处理,在提高海泡石纯度,分散海泡石纤维束、使海泡石结构中孔隙扩大,进而达到更多载入Zn2+目的等方面都是十分必要和有效的方法;采用干湿循环方式将Zn2+载于海泡石能提高海泡石的载Zn2+量,但干湿循环方式操作更复杂,能耗更大,应视具体情况酌情选择使用。  相似文献   

双能CT成像基材料分解法的理论误差分析     

郑鹏  郝佳  邢宇翔 《CT理论与应用研究》2011,20(2):153-162

双能X射线计算机断层成像技术(DECT)能够准确地重建物质的有效原子序数和电子密度信息,是一种有效的物质辨别技术.基材料分解法是求解DECT重建问题的主要方法之一.但目前应用此方法得到的重建结果误差较大,并且对于金属伪影抑制能力也较差.本文分析了DECT基材料分解法重建结果的误差来源和形成机制,阐释了其对金属伪影抑制作...  相似文献   

基于Voronoi的海洋底质区域划界方法研究     

王涛  陈惠荣  王少帅  魏涛 《测绘与空间地理信息》2011,34(1):242-243

在对Voronoi特性进行分析的基础上,运用Delaunay规则实现了海洋底质数据点的三角网化,从而间接生成了Voronoi图,再经过邻近区域的合并处理得到理想的底质划界区域。  相似文献   

基于DEA和Malmquist的中国城市代谢效率研究   总被引：5，自引：4，他引：1  

陈雪婷  宋涛  蔡建明  李玏  邓羽 《地理科学》2015,(4):419-426

运用物质流、数据包络分析(DEA)及Malmquist指数对中国31个案例城市进行了城市代谢效率的研究。通过将城市代谢系统社会经济产出、环境非期望产出及水、电、化石能源、金属矿物、建筑材料、食物等投入部分纳入进DEA和Malmquist指数中,测得了案例城市的2000年、2010年代谢效率及变化趋势。研究结果发现,中国城市代谢系统效率总体相对较高,尤其是东中部地区城市的综合效率、纯技术效率和规模效率要高于西部地区城市,大城市的代谢综合效率高于巨型、超大和特大城市。2000~2010年,城市代谢综合效率、纯技术效率等所有效率指标的均值均呈现出下降趋势,但是中、西部地区城市的综合效率和纯技术效率却呈改善趋势,并且特大和超大城市的综合效率高于巨型城市。  相似文献